Press Windows key + R and type “ control mlcfg32.cpl” to return to Mail Settings. Note: The default location of the PST file is in Documents / Outlook Files After you load it, click on Set as Default.
Once all the accounts are removed, click the Data Files tab, tap on Add and browse to your PST location. Note: The primary account can be identified via the check mark in the left-hand section of the screen. You can remove them by clicking on an account to select it and then clicking on Remove. Start with secondary accounts and leave the primary account for last. In Account Settings (Email tab) start removing your Outlook accounts. Once you’re inside Mail Setup, click on Email Accounts. Press Windows key + R and type “ control mlcfg32.cpl”. Close Outlook completely and all the associated dialogs. To make it easier for you, we have included below step-by-step guides with each of the methods presented above. The third option is to add a PST file to the default profile, set it as the new default and then remove the Exchange account\s. The second way would be to change some settings in the registry and then removing the primary Exchange account. However, you can go about removing the primary account in two other ways. If you’re in a situation like this, it’s recommended to create a new profile and add the account you want to set as primary first. When you remove the primary Exchange account, the next one (sorted by date) is automatically set as primary. You can’t remove a primary account from a profile unless you get rid of all the other Exchange accounts from that particular profile. 
Outlook operates by setting the first account added to a profile as the primary account. If you think about it, loading a new email account with a new data file should also override the old primary account preference, but it doesn’t. You must remove all other Exchange accounts before removing the primary account” ” The primary account cannot be removed unless it is the only account in the profile.
If you want to retain the current profile while trying to move from an internal Exchange server to the new Office 365, you’ll get a message saying that the primary account cannot be removed.
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